I learned today about a method of color photography invented in 1891, called the Lippmann plates. The Lippmann method is a beautiful hybrid of photography and holography. A layer of transparent gelatin with silver halide nanoparticles was applied to a glass plate, which was backed by a mirror made of liquid mercury (!). Light, passing through the glass, was reflected by the mercury, collided with itself, and created a standing wave. Inside the microscopic layer of gelatin, the light literally “froze,” burning silver nanostructures in strict accordance with the actual wavelength.
In all modern methods, color is achieved by overlaying three colors, just as on the screen from which you are reading this, red, blue, and green. Thus, there is no true yellow or purple in photographs. But on the Lippmann plate, all colors are real.
It’s also interesting that the Lippmann plate contains not a drop of pigment or dye. It is absolutely transparent! The color in it is born physically (due to structural interference) — just as the wings of butterflies or soap bubbles shimmer.
And obviously, you cannot make a copy from such a “photograph.” I’ll give a link to a good video below.
Indeed, this optical magic had its own quirks. Perfect mirror-like layers inside the plate were only obtained from pure, concentrated color. If a complex “dirty” or dull light entered the frame, the microstructures began to overlay each other, blurring the accuracy of color reproduction. Moreover, two opposite effects were born in the emulsion at the same time: the physical silver mirror created a colorful positive picture, but the silver itself remained just a regular black-and-white negative. Because of this optical conflict, the brightness of the frame was severely compressed, creating a vintage effect of a “hand-painted” photograph. Therefore, the method required jewel-like work with light and perfectly bright set pieces.












